Material
General
The material selection process shall ensure that the material is compatible with the service fluids to which it is exposed over the full design temperature range so that the mechanical, physical and chemical properties of the GRP satisfy the design requirements throughout the intended lifetime. Triplet shall provide the details of the raw materials and resin systems intended to be used for the project during the technical bid stage for the company Review and acceptance. Fiberglass pipe is a composite material system produced from glass fiber reinforcements, thermosetting plastic resins, and additives. By selecting the right combination and amount of materials and the specific manufacturing process, Triplet can create a product to meet the most demanding requirements.
The material system
The principal reinforcement material of the component wall shall be glass fibre, e.g. continuous E-Glass and/or woven rovings.
Fiberglass composites consist of glass fiber reinforcements, thermosetting resins, and additives, which are designed and processed to meet specific functional performance criteria. The following is a list of raw material used in describing the material system.
Fibre glass reinforcement
The amount, type, location, and orientation of glass fibers in the pipe that will provide the required mechanical strength.
The glass fibers most commonly used in pipe are referred to as Types E, ECR, and C. Glass types ECR and C provide improved acid and chemical resistance. Type C glass fibers are generally only used to reinforce chemical-resistant liners.
Resins
The second major component of fiberglass pipe is the resin system. Manufacturers choose a resin system for chemical, mechanical, and thermal properties and process ability. Fiberglass pipe, by definition, uses only thermosetting resin systems. Thermosets are polymeric resin systems cured by heat or chemical additives. Once cured, a thermoset is essentially infusible (cannot be remelted) and insoluble. The temperature range of different resins is shown in table.
Temperature limitations for GRP
| Type GRP | Design Temperature | Typical Tg value of fully cured resin |
|---|---|---|
| Glass-fibre/epoxy(GRE) | ||
| Aromatic-amine cured(MDA) | 100oC | 130oC |
| Cyclo-aliphatic cured(IPD) | 100oC | 130oC |
| Aliphatic-amine cured | 85oC | 115oC |
| Anhydride cured | 85oC | 115oC |
| Glass-fibre/vinyl ester (GRV) | 90oC | 120oC |
| Bisphenol A | 100oC | 140oC |
| Glass-fibre/polyester(GRP) | ||
| Isophthalic | 60oC | 90oC |
Polyester resin
Polyester resins are commonly used to produce large-diameter water and sewage piping. Polyesters have excellent water and chemical resistance and are noted for acid resistance. Polyester resins are cured by organic peroxide catalysts. The type and amount of catalyst will influence gel time, cure time, curing temperature, and the degree of cure. Isophthalic polyester resin is typically used. Isophthalic polyester is a relatively low cost resin, with limited chemical resistance
Vinyl ester Resin
Compared to polyester, vinyl ester resin has very good chemical resistance, especially against acids. High temperature and chemical resistant vinyl ester based resins, e.g. Novolac vinyl ester, are also available.
Epoxy resin
Epoxy resins are used to a wide range of moderately strong acids and alkalis, conveying water, condensates, hydrocarbons and caustics Fiberglass epoxy piping is used in oil fields at pressures up to several thousand per square inch (kilopascals). Epoxy resins cannot be categorized by resin type as easily as polyesters. The type of curing agent, or hardener, is critical with epoxy resins because the agent influences the composite properties and performance.
For optimum chemical resistance, these mixtures usually require a heat cure and/or post cure. The cured resin has good chemical resistance, particularly in alkaline environments, and can have good temperature resistance. There are several types of base epoxy resins and associated curing agents Curing agents typically used for epoxy resin are:
Chemical resistance of GRP material
| Fluid Type | GRE Aliphatic | GRE Aromatic | GRE Anhydride | GRV Vinyl ester | GRP Polyester |
|---|---|---|---|---|---|
| Acids | X | X | X | ? | X |
| Alkalis(Caustic) | ? | ? | X | ? | X |
| Solvents(BTX) | ? | ? | X | X | X |
| Water Sea/Brackish | ? | ? | ? | ? | ? |
